Teaching Single Crystal X-ray Crystallography in the Undergraduate Classroom with Sugar and Epsom Salt

We developed a single crystal X-ray crystallography experiment based on the crystal structure of sucrose (table sugar), and a more challenging experiment using Epsom salt. Both crystals are readily available in X-ray quality crystalline form. In these experiments, students mounted a crystal on a MiTeGen loop and analyzed it using a Rigaku XtaLAB Mini diffractometer (built 2011). Students generated models of both compounds using CrysAlisPro, Olex2, SHELXT, and SHELXL. All aspects of this experiment use free software programs which have user-friendly interfaces. A step-by-step laboratory protocol for determining the structure of both compounds is included in the Supporting Information. These experiments were used in the Fall of 2019 at the Junior and the Senior level. In the Summer of 2020, a take-home version of the lab was created in response to the Novel 2019 Coronavirus (COVID-19) pandemic and implemented in the General Chemistry laboratory curriculum;this experiment was used for the duration of the 2020-2021 academic year. These experiments are suitable for all undergraduate experience levels. © 2022 American Chemical Society and Division of Chemical Education, Inc.

How Partial Anonymity May Reduce Students' Anxiety During Remote Active Learning─A Case Study Using Clubhouse

Active learning, a common practice in higher education, has been shown to promote higher order thinking and skills. Class discussions have been chosen to be the medium to incorporate active learning in schools‘ curriculum. However, the rate of class participation could be low for certain courses. Literature has shown that the fear of negative evaluation from peers is the most common reason as to why students choose not to partake in class discussions. Anonymity via clickers or applications such as Kahoot! has shown to be useful in reducing students' anxiety and increasing class participations. However, this is not a viable method to employ if vocal discussion is required for the course. Here, partial anonymity (voice only), Speak Your Mind, was applied into an environmental chemistry course with 20 students in the National University of Singapore (NUS) to study its correlation with students‘ anxiety and class participation. Participants survey results suggested that a reason for not participating in class discussions was the fear of being judged by their peers. Remote learning was conducted due to COVID-19 and partial anonymity was obtained by a proxy application: Clubhouse. This application allowed students to partake in a podium discussion while maintaining psychological safety via partial anonymity. Participants survey responses indicated that partial anonymity reduced their anxiety (Cohen's d = 0.58) and slightly increased their self-reported class participation rate (Cohen's d = 0.21);it was noted that partial anonymity did not have much effect on their fears of being judged if they provided the wrong answer (Cohen's d = 0.11). © 2023 American Chemical Society and Division of Chemical Education, Inc.

Teaching Single Crystal X-ray Crystallography in the Undergraduate Classroom with Sugar and Epsom Salt

We developed a single crystal X-ray crystallography experiment based on the crystal structure of sucrose (table sugar), and a more challenging experiment using Epsom salt. Both crystals are readily available in X-ray quality crystalline form. In these experiments, students mounted a crystal on a MiTeGen loop and analyzed it using a Rigaku XtaLAB Mini diffractometer (built 2011). Students generated models of both compounds using CrysAlisPro, Olex2, SHELXT, and SHELXL. All aspects of this experiment use free software programs which have user-friendly interfaces. A step-by-step laboratory protocol for determining the structure of both compounds is included in the Supporting Information. These experiments were used in the Fall of 2019 at the Junior and the Senior level. In the Summer of 2020, a take-home version of the lab was created in response to the Novel 2019 Coronavirus (COVID-19) pandemic and implemented in the General Chemistry laboratory curriculum;this experiment was used for the duration of the 2020-2021 academic year. These experiments are suitable for all undergraduate experience levels. © 2022 American Chemical Society and Division of Chemical Education, Inc.

Development of Bioderived Alternatives to N95 Face Masks in a Remote Course-Based Undergraduate Research Experience

The high demand for N95 and surgical masks made of nonbiodegradable petroleum-based materials due to SARS-CoV-2 challenges the recycling industry and is proving to be unsustainable. Although woven fabric masks present a longer lifetime, they are less effective in protecting against viral particulates. Here, through an at-home course-based undergraduate research experience (CURE), we demonstrate that alginate and soy-based materials are attractive alternatives for mask fabrication: stacking calcium ion-cross-linked alginate films with soy protein isolate sheets enables electrostatic and size-exclusion filtration. State-of-the-art aerosol testing confirmed this conclusion. Furthermore, because our synthetic and at-home analytical approach relies on cheap, abundant, and food-grade materials, and requires no equipment beyond kitchenware, it has the potential to be broadly adopted for practical and educational purposes. © 2022 American Chemical Society and Division of Chemical Education, Inc.

Linking Chemistry to Community: Integration of Culturally Responsive Teaching into General Chemistry I Laboratory in a Remote Setting

The COVID-19 pandemic redefined how chemistry laboratories were taught. It also introduced a racial health disparity for Black and Brown people. The General Chemistry I laboratory curriculum at a Historically Black College and University (HBCU) in Baltimore, MD, was redesigned to meet student needs during this challenging time. While surrounded by civil unrest and uncertainty, we wanted to reach our underrepresented students in a way that they felt seen and heard. "The Mystery of Mr. Johnson" series was designed to reinforce the role chemistry can serve in advancing equity in their community. This interconnected series of three experiments (Solutions, Titration, Spectroscopy) developed chemistry laboratory skills which were applied to diabetes, a COVID-19 comorbidity, and health disparity highly prevalent in Baltimore. "The Mystery of Mr. Johnson" series provided opportunities for students to gain exposure to the role of chemistry in addressing a health disparity that impacts their community. The culminating project was a public service announcement to communicate lifestyle changes and the prevalence of diabetes in the black community.